PRINCIPLES OF INDUSTRIAL CHEMISTRY
cod. 1001439

Academic year 2023/24
2° year of course - Second semester
Professor
Nicola DELLA CA'
Academic discipline
Chimica industriale (CHIM/04)
Field
Attività formative affini o integrative
Type of training activity
Related/supplementary
52 hours
of face-to-face activities
6 credits
hub: PARMA
course unit
in ITALIAN

Learning objectives

At the end of the course the student will acquire a deep knowledge of the essential principles and general criteria which are crucial for the realization of an industrial chemical process. For this purpose specific chemical processes will be described and analyzed from the thermodynamic and kinetic point of view and the most important technological aspects will be highlighted as well. The problems connected with the cost, sustainability and safety of an industrial process will also be treated (Knowledge and understanding).

The student will be able to analyze from an thermodynamic and kinetic point of view an industrial process, to choose the optimal parameters for the conduction of a chemical process. He will be able to perform basic mass and energy balance calculations. He will be able to safely use chemicals and to dispose them properly. (Applying knowledge and understanding).

He will be able to critically evaluate safety and economy aspects of a chemical process, and those related to products and materials. He will critically choose the optimal production technologies. He will be able to correlate the data acquired experimentally with theoretical models (Making judgments).

The student acquires the ability to communicate, both in oral and written form, with a technical-specialist language that allows him to dialogue with chemists and other professional figures. He will be able to interact with other staff on the implementation of the necessary safety measures in the chemical field (Communication skills).

The student will be able to undertake academic studies of higher level with a sufficient degree of autonomy or to continue his professional training. He will acquire teem-working and problem solving skills, and the ability to work in autonomy as well. He will be able to adapt to different working environments and will also be able to interpret, in an autonomous way, data of technical-scientific literature. (Learning skills)

Prerequisites

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Course unit content

Elements of thermodynamics and kinetics: finding the right operating conditions (pressure, temperature, contact time) for a specific industrial chemical process. Concepts of yield, conversion and selectivity. Parallel and consecutive reactions. Examples of recycling, by-pass and purge. Selection and design of a reactor in continuous or discontinuous operation mode. Multiphase reactions. Use of homogeneous and heterogeneous catalysts in industrial field. From laboratory to industry: problems associated with the scale-up. Importance of availability of raw materials, sustainability and safety of a chemical plant. Considerations on the overall costs (fixed and variable) of a process. Mass and energy balances applied to chemical industry.
The aspects described will be illustrated with industrial processes listed below:
-Liquefaction of gases. Separation of air gases.
-Hydrogen production and syngas.
-Methanol industrial production
-Fischer-Tropsch process
-Haber-Bosch process
-Urea production
-Ostwald process
-Sulforic acid production
-Claus process
-Leblanc and Solvay processes
-Chloro-alkali industry: chlorine and sodium hydroxide production
-Examples from Petrochemical industry: Steam cracking, Reforming catalitico, Hydrotreating, Catalytic cracking.

Full programme

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Bibliography

1) "Chimica Industriale Inorganica" Vol I e "Chimica Industriale Organica" Vol II (Stocchi, Edisco)
2) "Chimica Inorganica Industriale" C. Botteghi (Piccin)
3) "An Introduction to Industrial Chemistry" C. A. Heaton
4) "Organic Chemistry: Principles and Industrial Practice" Mark M. Green, Harold A. Wittcoff
5) “Fundamentals of Industrial catalytic processes” C.H. Bartholomew, R.J. Ferrauto
6) "Principi della Chimica Industriale" Vol. I e II G. Natta, L. Pasquon
7) "Fondamenti di chimica industriale", Cavani, Centi, Di Serio, Rossetti, Salvini, Strukul (Zanichelli, 2022)

Teaching methods

The course is composed of 52 hours of lessons, during which students are guided to the understanding of the basic principles of Industrial Chemistry. During the lessons the general problems associated with the
conduction of a chemical reaction on industrial scale will be discussed. The theoretical concepts will be exemplified with some industrial processes of great importance. The slides used will be uploaded weekly
on the Elly platform. Additional material is also available on Elly. To download the slides you need to subscribe to the online course. Slides are considered an integral part of the teaching material. It reminds non-attending students to check the available teaching material and the guidelines provided by the teacher through the Elly platform. The teacher is available by appointment (e-mail) for explanations.

Assessment methods and criteria

Knowledge and understanding of the concepts are verified by oral examination. The student must demonstrate: 1) to understand the industrial chemical processes in all their aspects. 2) to be able to compare and discuss the processes individually and in a critical way: for example, compare a dated process with a more innovative. 3) to use a proper language to describe the processes. 4) to be able to find connections among contents of other courses: for example to explain in terms of thermodynamic and kinetic reaction of an industrial process using the skills acquired in the courses of General and Inorganic Chemistry and Physical Chemistry I. The synthesis, the use of proper technical language and communication skills will be evaluated positively. We will decide the day of the oral examination by email. The score of the oral test is immediately communicated. Please note that online registration on ESSE3 is mandatory.

Other information

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