SOLID STATE PHYSICAL CHEMISTRY
cod. 00123

Academic year 2009/10
1° year of course - Second semester
Professor
Academic discipline
Chimica fisica (CHIM/02)
Field
Discipline chimiche inorganiche e chimico-fisiche
Type of training activity
Characterising
48 hours
of face-to-face activities
6 credits
hub:
course unit
in - - -

Learning objectives

<br />At the end of the course the students will be able to indipendently perform and analyze spectroscopic experiments in the field of molecular crystals 

Prerequisites

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Course unit content

<br /><br />Optical properties of molecular solids<br />Electromagnetic theory; Absorbance and reflectance of crystal surfaces. Kramers-Kronig dipersion relations; absorption coefficents, refraction index, optical conductivity and dielectric function<br />Optical spectra of synthetic metals: Drude model; band structure model. Electron-electron and electron-phonon interactions.<br /><br />Optica spectra of molecular crystals (semiconductors): Interband transitions. Collective electronic states; molecular excitons; electron-phonon interactions.<br />Symmetry in crystals: Factor group analysis; oriented gas model. <br />Phonons in molecular crystals:  Intramolecular vibrations and lattice vibrations <br />Phase transitions<br />Experimental methods<br />Main spectroscopic technique: UV-VIS e IR spectroscopy; Raman spectroscopy. Cryogenic and high pressure (diamond anvil cell) techniques.<br /><br />Lab Experiences<br />Lab experiences will focus on one topics to be chosen by students

Full programme

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Bibliography

<br />J.C.Decius and R.M.Hexter "Molecular vibrations in crystals" (McGraw-Hill 1977).<br />G. Turrell "Infrared and Raman properties of crystals" (Academic Press 1972).<br />H. Kuzmany "Solid State Spectroscopy" (Springer 1998).<br />M.Dressel and G.Gruner "Electrodynamics of solids" (Cambridge 2002).<br />Review and research papers easily accessible in the local scientific library 

Teaching methods

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Assessment methods and criteria

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Other information

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