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University of Parma
Course catalogue
Università degli Studi di Parma
course catalogue

LABORATORY FOR INORGANIC CHEMISTRY
cod. 07272

Academic year 2008/09
2° year of course - First semester
Professor
Academic discipline
Chimica generale e inorganica (CHIM/03)
Field
Discipline inorganiche chimico fisiche
Type of training activity
Characterising
30 hours
of face-to-face activities
2 credits
hub: -
course unit
in - - -
lectures timetable unavailable
exam calls

Integrated course unit module: INORGANIC CHEMISTRY-INORGANIC CHEMISTRY LAB.

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Learning objectives

To provide the students with fundamentals of synthesis and characterization of inorganic and coordination compounds

Prerequisites

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Course unit content

<p> Laboratory<br />
<br />
1. Sinthesis of cis/trans-bis(glycinate)Cu(II). Characterization through IR spectroscopy. <br />
<br />
Concepts: chelate effect; stereochemical properties of Cu(II); kinetics and thermodynamic of formation of the products <br />
<br />
2. Preparation of a N,N bidentate CH2PzPy ligand through phase transfer catalysis. Preparation of the [ZnCl2(CH2PzPy)] complex.<br />
<br />
Concepts: properties of Zn2+ ion , phase transfer catalysis, bidimensional NMR <br />
<br />
3. Synthesis of tris(acetiacetonate)Al(III). Characterization by NMR spectroscopy.<br />
<br />
Concepts: properties of Al(III), Hard-Soft Theory , acetilacetone as ligand, keto/enolic tautomery , stereoisomery and chirality <br />
<br />
4. Preparation of the d-tris(ethylenediamine)cobalt(III) through a partial asymmetric sinthesis<br />
<br />
Concepts: properties of Co(III), lability and inertness of coordination compounds, asymmetric synthesis, chirality. </p>
<p><br />
Coordination compounds<br />
<br />
Spectroscopy, theory <br />
<br />
Electromagnetic spectrum, matter-radiations interaction, Boltzmann distribution<br />
<br />
Spectroscopy, techniques<br />
<br />
NMR <br />
<br />
spin angular/magnetic moment , chemical shift, FT-NMR, NMR in inorganic chemistry</p>
<p>IR <br />
<br />
infrared radiation and vibrational energy, normal modes, correlation between molecular structure and IR bands, FT-IR, Michelson interferometer. IR Spectroscopy and coordination compounds; free and coordinated ligand, cis-trans isomery, simmetry, carbonil as ligand (CO) </p>
<p>UV-Vis <br />
<br />
electronic spectra of coordination compounds, absorbance (A) and transmittance <br />
</p>

Full programme

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Bibliography

<p>Material provided by the teacher</p>

Teaching methods

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Assessment methods and criteria

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Other information

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