METALORGANIC CHEMISTRY
cod. 07507

Academic year 2009/10
1° year of course - First semester
Professor
Academic discipline
Chimica generale e inorganica (CHIM/03)
Field
Discipline chimiche
Type of training activity
Characterising
48 hours
of face-to-face activities
6 credits
hub:
course unit
in - - -

Learning objectives

<p>To provide the student with the basic knowledge on the preparation , structure, reactivity and characterization of the most important organometallic compounds</p>

Prerequisites

Knowledge acquired in the courses of: General and Inorganic Chemistry, Inorganic Chemistry, Organic Chemistry I, Organic Chemistry II

Course unit content

<p>Complexes with transition Metal-Carbon sigma bonds</p>
<p>Complexes with Transition Metal-Carbon pi-bonds</p>
<p>General Introduction</p>
<p>Metal carbonyl complexes</p>
<p>Metal alkyl complexes</p>
<p>Carbene, alkylidene and alkylidyne complexes</p>
<p>Alkene and alkyne complexes</p>
<p>Cyclopentadienyl and arene complexes <br />
<br />
Allyl and dienyl complexes<br />
<br />
Basics of characterization of organometallic compounds by means of infrared spectrophotometry and multinuclear NMR.<br />
<br />
<br />
<br />
<br />
</p>

Full programme

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Bibliography

Manfred Bochmann; Organometallics 1, Organometallics 2; Oxford Science Publications <br />
<br />
Christoph Elschenbroich; Organometallics (Third edition); Wiley-VCH <br />

Teaching methods

<p>Discussion of a recent scientific paper on organometallic chemistry</p>
<p>Oral exam on the course subjects</p>

Assessment methods and criteria

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Other information

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